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章末排查练(三)授课提示：对应学生用书第75页排查50个重要反应的化学、离子方程式1．钠及其重要化合物①Na和H2O的反应________________________________________________________________________

②Na和CH3COOH的反应________________________________________________________________________③Na2O2和H2O的反应_________________________________________

_______________________________④NaH和水的反应________________________________________________________________________⑤向NaOH溶液

中通入过量CO2________________________________________________________________________⑥将Na2CO3溶液与石灰乳混合________

________________________________________________________________⑦向Na2CO3溶液中通入过量CO2________________________________________________________

________________⑧将Na2CO3和Ca(HCO3)2混合________________________________________________________________________⑨将含等物质的

量NaHCO3溶液和NaOH溶液混合________________________________________________________________________⑩将含等物质的量NaHCO3溶液与澄清石灰水混合____________

____________________________________________________________⑪将NaHCO3溶液与少量澄清石灰水混合______________________

__________________________________________________⑫向饱和Na2CO3溶液中通入过量CO2气体__________________________________________________________

______________答案：①2Na＋2H2O===2Na＋＋2OH－＋H2↑②2Na＋2CH3COOH===2CH3COO－＋2Na＋＋H2↑③2Na2O2＋2H2O===4Na＋＋4OH－＋O2↑④NaH＋

H2O===Na＋＋OH－＋H2↑⑤OH－＋CO2===HCO－3⑥CO2－3＋Ca(OH)2===CaCO3↓＋2OH－⑦CO2－3＋CO2＋H2O===2HCO－3⑧CO2－3＋Ca2＋===CaCO3↓⑨HCO－3＋OH－===CO2－3＋H2O⑩HCO－

3＋Ca2＋＋OH－===CaCO3↓＋H2O⑪2HCO－3＋Ca2＋＋2OH－===CaCO3↓＋CO2－3＋2H2O⑫2Na＋＋CO2－3＋CO2＋H2O===2NaHCO3↓2．铝及其重要化合物⑬Al和NaOH溶液的反应___

_____________________________________________________________________⑭Al(OH)3和NaOH溶液的反应_______________________________________________________

_________________⑮Al(OH)3和盐酸的反应________________________________________________________________________⑯Al2O3和NaOH的反应__

______________________________________________________________________⑰Al2O3和盐酸的反应_______________________________________

_________________________________⑱NaAlO2和过量盐酸的反应_____________________________________________________________

___________⑲向NaAlO2溶液中通入过量CO2气体________________________________________________________________________⑳将NaAlO2与NaHCO3混合____

____________________________________________________________________○21将NaAlO2与AlCl3溶液混合_________________________________________________________

_______________○22向AlCl3溶液中加入过量NaOH溶液________________________________________________________________________○23向AlCl3溶液中加入过量氨水_

_______________________________________________________________________○24将AlCl3溶液与NaHCO3溶液混合__________________________________________________

______________________答案：⑬2Al＋2OH－＋2H2O===2AlO－2＋3H2↑⑭Al(OH)3＋OH－===AlO－2＋2H2O⑮Al(OH)3＋3H＋===Al3＋＋3H2O⑯Al2O3＋2OH－===2AlO－2＋H2

O⑰Al2O3＋6H＋===2Al3＋＋3H2O⑱AlO－2＋4H＋===Al3＋＋2H2O⑲AlO－2＋CO2＋2H2O===Al(OH)3↓＋HCO－3⑳AlO－2＋HCO－3＋H2O===Al(OH)3↓＋CO2－3○21

213AlO－2＋Al3＋＋6H2O===4Al(OH)3↓○22Al3＋＋4OH－===AlO－2＋2H2O○23Al3＋＋3NH3·H2O===Al(OH)3↓＋3NH＋4○24Al3＋＋3HCO－3===Al

(OH)3↓＋3CO2↑3．铁及其重要化合物○25Fe和过量稀HNO3的反应________________________________________________________________________○26Fe高温下和

水蒸气的反应________________________________________________________________________○27Fe2O3和Al的反应___________________________

_____________________________________________○28Fe2O3高温下和CO的反应______________________________________________

__________________________○29FeCl3溶液和Cu的反应________________________________________________________________________○30FeCl3与

KSCN的反应________________________________________________________________________○31向FeCl2溶液中加入等物质的量的Na2O2____________

____________________________________________________________○32向FeCl2溶液中加入NaClO_______________________________________________________________

_________○33Fe(OH)2长时间置于空气中________________________________________________________________________○34Fe3O4和稀盐

酸的反应________________________________________________________________________○35Fe3O4和稀HNO3的反应____________

____________________________________________________________○36FeO和稀盐酸的反应_____________________________________________

___________________________○37FeO和稀HNO3的反应__________________________________________________________________

______○38Fe(OH)2和稀盐酸的反应________________________________________________________________________○39Fe(OH)2和稀HNO3的反应____________________

____________________________________________________○40Fe(OH)3和HI的反应_______________________________________________

_________________________○41FeBr2和少量Cl2的反应________________________________________________________________________○42FeBr2和Cl2等物质的量的反

应________________________________________________________________________○43FeBr2和过量Cl2的反应_______________________________________

_________________________________答案：○25Fe＋4H＋＋NO－3===Fe3＋＋NO↑＋2H2O○263Fe＋4H2O(g)=====高温Fe3O4＋4H2○27Fe2O3＋2Al=====高温2Fe＋Al2O

3○28Fe2O3＋3CO=====高温2Fe＋3CO2○292Fe3＋＋Cu===2Fe2＋＋Cu2＋○30Fe3＋＋3SCN－Fe(SCN)3○314Fe2＋＋4Na2O2＋6H2O===4Fe(OH)3↓＋8Na＋＋O2↑○322Fe2＋＋

ClO－＋4OH－＋H2O===2Fe(OH)3↓＋Cl－○334Fe(OH)2＋O2＋2H2O===4Fe(OH)3○34Fe3O4＋8H＋===2Fe3＋＋Fe2＋＋4H2O○353Fe3O4＋28H＋＋NO－3===9Fe3＋＋NO↑＋14H2O○36FeO＋2H＋==

=Fe2＋＋H2O○373FeO＋10H＋＋NO－3===3Fe3＋＋NO↑＋5H2O○38Fe(OH)2＋2H＋===Fe2＋＋2H2O○393Fe(OH)2＋10H＋＋NO－3===3Fe3＋＋NO↑＋8H2O○402Fe(OH)3

＋6H＋＋2I－===2Fe2＋＋I2＋6H2O○412Fe2＋＋Cl2===2Fe3＋＋2Cl－○422Fe2＋＋2Br－＋2Cl2===2Fe3＋＋Br2＋4Cl－○432Fe2＋＋4Br－＋3Cl2===2Fe3＋＋2Br2＋6Cl－4．铜及其重要化合物○44Cu在硫

蒸气中燃烧________________________________________________________________________○45铜在空气中生成铜绿________________________

________________________________________________○46用惰性电极电解CuSO4溶液_______________________________________________________

_________________○47Cu和浓HNO3的反应_____________________________________________________________________

___○48Cu和稀HNO3的反应________________________________________________________________________○49Cu和浓H2SO4的反应____________________________

____________________________________________○50胆矾受热分解_________________________________________________________________

_______答案：○442Cu＋S=====△Cu2S○452Cu＋O2＋CO2＋H2O===Cu2(OH)2CO3○462Cu2＋＋2H2O=====通电2Cu＋4H＋＋O2↑○47Cu＋4H＋＋2NO－3===Cu2＋＋2N

O2↑＋2H2O○483Cu＋8H＋＋2NO－3===3Cu2＋＋2NO↑＋4H2O○49Cu＋2H2SO4(浓)=====△Cu2＋＋SO2－4＋SO2↑＋2H2O